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Of the four stereoisomers (+ )-i|i-ephedrine and ephedrine are pharmacologically active, being ephedrine of more commercial value .
A synthetic route producing a predominance of the (-)-isomer was desired, and this was achieved by ephedrine the reductive amination of phenylacetylcarbinol (9) with methylamine and hydrogen over a platinum catalyst 10 , Scheme 4 .
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